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A New Convergent Approach to α-Branched Alkynes.

✍ Scribed by Delphine Renard; Hadi Rezaei; Samir Z. Zard


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
33
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


📜 SIMILAR VOLUMES


ChemInform Abstract: A Convergent Approa
✍ J. BOIVIN; S. HUPPE; S. Z. ZARD 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

The convergent approach to a broad variety of functionalized alkynes starts with a Knoevenagel-type condensation of 4-unsubstituted isoxazolines with ketones or aldehydes. The resulting adducts are subjected to Michael addition with various nucleophiles such as hydride, cyanide or phosphite. Exposur