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A new chiral ligand for the Fe–Lewis acid catalysed asymmetric Diels–Alder reaction

✍ Scribed by Bruin, Marion E.; Peter Kündig, E.

Book ID
120342222
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
90 KB
Volume
23
Category
Article
ISSN
1359-7345

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📜 SIMILAR VOLUMES

Asymmetric Diels-Alder reaction catalyse
Asymmetric Diels-Alder reaction catalysed by some chiral Lewis acids
✍ F. Rebiere; O. Riant; H.B. Kagan 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 906 KB

Diels-Alder reaction between cyclopentadiene and various dienophiles (mainly methacrolein) at -78°C was catalysed by various chiral aluminum alcoholates. The catalysts were prepared by reaction of EtAICl2 with several families of dial (or their monoether monoalcohol derivatives) . The most enantiose