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Bronsted Acid Assisted Chiral Lewis Acid (BLA) Catalyst for Asymmetric Diels-Alder Reaction

✍ Scribed by Ishihara, Kazuaki; Yamamoto, Hisashi


Book ID
120032720
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
281 KB
Volume
116
Category
Article
ISSN
0002-7863

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📜 SIMILAR VOLUMES


Asymmetric Diels-Alder reaction catalyse
✍ F. Rebiere; O. Riant; H.B. Kagan 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 906 KB

Diels-Alder reaction between cyclopentadiene and various dienophiles (mainly methacrolein) at -78°C was catalysed by various chiral aluminum alcoholates. The catalysts were prepared by reaction of EtAICl2 with several families of dial (or their monoether monoalcohol derivatives) . The most enantiose