Various 6-O-acylsucroses were synthesized in good yields from unprotected sucrose in N,N-dimethylformamide and the appropriate 3-acylthiazolidine-2-thiones 6 or 3-acyl-5-methyl-1,3,4-thiadiazole-2(3H)-thiones 7. A selective ionization of the free sugar by sodium hydride or triethylamine, followed by
A new chemoenzymatic synthesis of 6′-O-acylsucroses.
✍ Scribed by Caroline Chauvin; Daniel Plusquellec
- Book ID
- 103401388
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 282 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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