A new chemical synthesis of Ascopyrone P from 1,5-anhydro-d-fructose
β Scribed by Mikkel Andreassen; Inge Lundt
- Book ID
- 108080353
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 127 KB
- Volume
- 341
- Category
- Article
- ISSN
- 0008-6215
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3,4-O-Isopropylidene-D-lyxo-hexopyranosid-2-ulose derivatives, obtained by oxidation of 3,4,6-protected D-galactopyranosides, can be alkylated in their anionic 2,6-pyranose forms to produce bis-glycosides containing the 2,5-dioxabicyclo[2.2.2]octane ring system. The 1-benzyl-2methyl bis-glycoside 4b