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Synthesis of amino-1,4-anhydro-d-pentitols and amino-1,5-anhydro-d-hexitols with the arabino configuration from (R)-glycidol

✍ Scribed by Sı́lvia Aragonès; Fernando Bravo; Yolanda Dı́az; Ma̱ Isabel Matheu; Sergio Castillón

Book ID
104359864
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
227 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

2-Amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration were synthesised from (R)-glycidol using a metathesis reaction as the key step. The dihydrofuran or dihydropyran products obtained after the metathesis reaction were subjected to epoxidation, epoxide opening with azide anion and finally azide reduction.

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