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A new chemical synthesis of 5α-cholest-8(14)-en-3β,5α-diol

✍ Scribed by Edward J Parish; Chi Luo; Terrence L Boos


Book ID
108313213
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
57 KB
Volume
109
Category
Article
ISSN
0009-3084

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The X-ray crystal structure of 3~-benzoyloxy-6a-chloro-5a-cholest-7-ene (IV) was determined by the heavy atom method and ref'med to R ---0.063 (space group P2s, a --11.364, b = 11.089, c --12.232,/~ = 99.43 °, Z ---2). IV was previously shown to be an important intermediate in the acid-catalyzed iso