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A novel reductive rearrangement of an α,β-unsaturated steroidal epoxide. A new synthesis of 5α-cholest-8(14)-en-3β,15α-diol

✍ Scribed by E.J. Parish; C.J. Schroepfer Jr.

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
189 KB
Volume
17
Category
Article
ISSN
0040-4039

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Sterol synthesis. A novel reductive rear
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The chemical synthesis of 3 beta-p-bromobenzoyloxy-15 beta-methyl-5 alpha,14 beta-cholest-7-en-15 alpha-ol from 15 beta-methyl-5 alpha, 14 beta-cholest-7-ene-3 beta,15 alpha-diol is described. The structure of the former compound was unambiguously determined by X-ray crystallographic analysis. The s