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A new channel-forming host macroring. X-ray crystal structure of its inclusion compound with DMF

✍ Scribed by Weber, Edwin; Pollex, Rolf; Czugler, Matyas


Book ID
126249923
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
395 KB
Volume
57
Category
Article
ISSN
0022-3263

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In 1,3-dimethyl-2-imidazolidinone (DMEU) as solvent, pentafluoropyridine reacts with PhSNa to give an essentially quantitative yield of pentakis(phenylthio)pyridine (l\_); however, analogous reaction with pentachloropyridine leads to the unexpected co-formation of the title compound (a), a new host