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Discovery and x-ray crystal structure of a new host compound: 1,3,4-tris(phenylthio)[1]benzothieno[3,2-c]pyridine

✍ Scribed by Christopher J. Gilmore; David D. MacNicol; Anthony Murphy; Marie A. Russell

Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 254 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81423-4

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✦ Synopsis

In 1,3-dimethyl-2-imidazolidinone (DMEU) as solvent, pentafluoropyridine reacts with PhSNa to give an essentially quantitative yield of pentakis(phenylthio)pyridine (l_); however, analogous reaction with pentachloropyridine leads to the unexpected co-formation of the title compound (a), a new host whose crystal structure has been elucidated by X-ray methods for both the unsolvated crystal and for the chlorobenzene inclusion compound.

We have recently shown that hexakis(arylthio)benzenes,' hexakis(aryloxy)benzenes, 2 and octakis(arylthio)naphthalenes, 3,4 classes of molecule of great

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