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A new bisannulation reagent easily prepared from a butadiene telomer, and its application to steroid synthesis

โœ Scribed by Tsuji, Jiro; Shimizu, Isao; Suzuki, Hirohisa; Naito, Yoichiro


Book ID
121449169
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
392 KB
Volume
101
Category
Article
ISSN
0002-7863

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Reaction of 1,7-octadien-3-one with dimethyl malonate, followed by the reduction of the ketone produced dimethyl (3-hydroxy-7-octenyl)malonate, which was converted to 9-decen-5-olide after hydrolysis and decarboxylation. Reaction