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A new approach to the synthesis of 2-amino-2-deoxyglycosides

โœ Scribed by R.U. Lemieux; T.L. Nagabhushan; I.K. O'Neill

Publisher
Elsevier Science
Year
1964
Tongue
French
Weight
427 KB
Volume
5
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The recent publication by Serfontein, Jordaan and White (1) on the nitrosyl chloride addition products of glycals prompts us to report at this time the results of our own investigations along similar lines. Addition of nitrosyl chloride to 3,4,6-tri-O-acetyl-Dglucal, in either methylene chloride or ether at -8O"C, provided in near quantitative yields the compound (I) reported by Serfontein et al as 3,4,6-tri-O-acetyl-2-nitroso-2-deoxy-a-D--glucopyranosyl chloride. After three recrystallizations from

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## Abstract For Abstract see ChemInform Abstract in Full Text.