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A new approach to the synthesis of 4,4-disubstituted -2-cyclohexenone

✍ Scribed by D. Becker; J. Kalo


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
99 KB
Volume
12
Category
Article
ISSN
0040-4039

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A new 4-substituted-2-Cyclohexenone synt
✍ Kevin I. Booker-Milburn; David F. Thompson πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 199 KB

Conjugate addition of a variety of Grignard reagents to 2-cyclopentenone followed by cyclopropanation of the resulting enol ethers gave a range of substituted cyclopropyl silyl ethers in good yield. Treatment of these cyclopropyl silyl ethers with ferric chloride in DMF gave the one carbon ring expa