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A New Approach to Highly Substituted Cyclopentanoids from a Concise Formal Synthesis of (+)-Roseophilin

✍ Scribed by Kerr, Daniel J.; Flynn, Bernard L.


Book ID
120245238
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
390 KB
Volume
14
Category
Article
ISSN
1523-7060

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πŸ“œ SIMILAR VOLUMES


ChemInform Abstract: Total Synthesis of
✍ A. FUERSTNER; H. WEINTRITT πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 2 views

Total Synthesis of the Potent Antitumor Agent Roseophilin: A Concise Approach to the Macrotricyclic Core. -The first synthesis of the intricate macrotricyclic core segment (XIV) of the title antibiotic is presented. The approach merges the potential of an established Pd-catalyzed macrocyclization r

Stereocontrolled approach to highly subs
✍ Susanta Samajdar; Debasis Patra; Subrata Ghosh πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 French βš– 697 KB

A direct stereocontrolled route for the construction of highly substituted cyclopentanones 10a-d has been developed starting from aeyclic ketones 5a,b. The key step involves copper(I)-eatalysed stezeoselective photocycloaddition of the dienes 6a-d followed by stereospecific rearrangement of the cycl