The key step in this concise and flexible method for the synthesis of biologically interesting piperidine alkaloids such as 1-deoxy-azasugars (VII) and (X) is the kinetic asymmetric resolution under modified Sharpless conditions to compounds (S)-(I) and (II). It is noteworthy that the synthesis of t
โฆ LIBER โฆ
A new approach to 1-deoxy-azasugars: Asymmetric synthesis of deoxymannojirimycin
โ Scribed by Yi-Ming Xu; Wei-Shan Zhou
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 154 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4039
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As a part of our work on the use of enulose derivatives, obtained from aldehydo sugars either by the Knoevenagel-Doebner reaction' or by the Wittig reaction\*, as starting products for the synthesis of hexulosesl, l-deoxyhexuloses1,3, and branched-chain deoxyhexuloses4, the title compounds were requ