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A new and facile synthetic route to N5-formyl tetrahydropteroylpoly-L-glutamates

✍ Scribed by Anthony L. Fitzhugh; Gwendolyn N. Chmurny; John R. Klose

Book ID: 108477010
Publisher: Elsevier Science
Year: 1991
Tongue: English
Weight: 277 KB
Volume: 1
Category: Article
ISSN: 0960-894X
DOI: 10.1016/s0960-894x(01)80789-7

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## Abstract The Wittig olefinations of 2,3‐__O__‐isopropylidene‐D‐ribofuranose (1) with two equivalents of alkylidenetriphenylphosphorane (alkylidene: hexylidene — undecylidene) followed by hydrogenation catalyzed by palladium on carbon and subsequent deprotection yield (2__R__,3__S__,4__S__‐(“L‐”_