A Facile Synthetic Route to New Fluorinated Building-Blocks of 1-Fluoroalkynes and 1-Fluorodiynes
β Scribed by Cuibo Liu; Hai Ma; Jing Nie; Junan Ma
- Publisher
- John Wiley and Sons
- Year
- 2012
- Tongue
- English
- Weight
- 363 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0256-7660
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## Abstract The treatment of the Ξ±βoxoketene dithioacetal sugar derivatives 2 and 7 with concentrated hydrochloric acid in THF leads to the openβchain uloses 3 and 8. The reaction mechanism can be rationalized as a retroβaldol reaction. This rationalization was supported by reacting 2 and 7 with DC
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