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A new and extremely efficient, general strategy for the synthesis of enantiomerically pure iridoid aglycones

✍ Scribed by José Marco-Contelles; Juliana Ruiz


Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
146 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis


A new and efficient approach for the synthesis of chiral iridoid aglycones is described.


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✍ F. Chrétien; M. Khaldi; Y. Chapleur 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 241 KB

Branched-chain cyciohexenones and cyclopentenones were prepared from sugar lactones by amide enolate condensation and subsequent intramolecular Knoevenagei reaction. Depending on the conditions, either the six-or the five-membered rings can be prepared from the same progenitor © 1997 Elsevier Scienc