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A new and efficient preparation of α,β-dehydroamino acids

✍ Scribed by Karen Goodall; Andrew F Parsons


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
117 KB
Volume
36
Category
Article
ISSN
0040-4039

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Efficient asymmetric synthesis of α-amin
✍ Tatsuhiko Kanmera; Sannamu Lee; Haruhiko Aoyagi; Nobuo Izumiya 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 290 KB

A series of cycZo(Aaminoacyl-L-Ala) (fl) (A=a,@dehydro) were prepared from cycZo(Gly-L-Ala) and corresponding aldehyde, and hydrogenated with Pd black in MeOH. Chiral inductions producing CycZo(L-aminoacyl-L-Ala) (2) from 2 were 96-99% in the case of L-Aba (2-eminobutanoic acid), L-Val, L-Leu, and L