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A new ambident cation. Reactions of 2-dialkylamino-1,3-dithiolanylium salts with various nucleophiles

โœ Scribed by Takeshi Nakai; Makoto Okawara


Book ID
104213223
Publisher
Elsevier Science
Year
1967
Tongue
French
Weight
188 KB
Volume
8
Category
Article
ISSN
0040-4039

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## Abstract The reaction of 1,2โ€diazaโ€1,3โ€butadienes with dibenzyl diisopropylphosphoramidite, methyl tetraisopropylphosphorodiamidite or tris(dimethylamino)phosphane under solventโ€free conditions gave stable ฮฑโ€phosphoranylideneโ€hydrazones that, in turn, were transformed into the corresponding 5โ€ox