A Mononuclear Paramagnetic Biphosphinotricarbonyl-cobalt(0) Complex
✍ Scribed by Dr. Dieter Fenske
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 227 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.009 A Ê Disorder in solvent or counterion R factor = 0.048 wR factor = 0.119 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Complexes (dad)~2~RuCl~2~ (1) (dad = diazadiene, RN = CR'– CR'=NR) are reduced to (dad)~2~Ru (2) which react with L = CO or ethylene to give (dad)~2~RuL (3,5). Reduction of 1b ( R' = H) with magnesium–butadiene or reaction of 2b with butadiene leads to a new type of C–C coupling of butadiene to one