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A mononuclear cobalt(III) complex of the ligand N,N′-bis­(pyridin-2-yl­methyl)­pyrazine-2,3-dicarbox­amide

✍ Scribed by Cati, Dilovan S. ;Stoeckli-Evans, Helen

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
563 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.009 A Ê Disorder in solvent or counterion R factor = 0.048 wR factor = 0.119 Data-to-parameter ratio = 12.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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## Abstract As a probe of the dinucleating ability of the known but little studied bis‐bidentate ligand 3,5‐di(2‐pyridyl)‐4‐(1__H__‐pyrrol‐1‐yl)‐4__H__‐1,2,4‐triazole (pldpt) its reactivity towards MX~2~·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^–^ and BF~4~^–^) as well as Cu(ClO~4~)~2~·6H~