๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

A Molybdenyl Chloromonophosphate with an Intersecting Tunnel Structure: Ba3Li2Cl2(MoO)4(PO4)6

โœ Scribed by M.M Borel; A Leclaire; J Chardon; J Provost; B Raveau

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
603 KB
Volume
141
Category
Article
ISSN
0022-4596

No coin nor oath required. For personal study only.

โœฆ Synopsis

A new molybdenyl chloromonophosphate, Ba 3 Li 2 Cl 2 (MoO) 4 (PO 4 ) 6 , has been synthesized. It crystallizes in the space group P2 1 2 1 2 1 , with a โ€ซุโ€ฌ 9.1768(4), b โ€ซุโ€ฌ 15.660(1), and c โ€ซุโ€ฌ 18.117(2) A s . This original pseudotetragonal structure forms an intersecting tunnel framework [Mo 4 P 6 O 28 ] built up from [Mo 2 P 2 O 12 ] layers interconnected through single PO 4 tetrahedra. The [Mo 2 P 2 O 12 ] layers derive from the perovskite structure by replacing one octahedron out of two by one PO 4 tetrahedron. The Li ุ‰ , Ba 2ุ‰ , and Cl\ species are distributed in the [100], [001], [201], and [201 ] tunnels forming intersecting rows. Two sorts of polyhedra are found for Li ุ‰ : LiO 3 Cl tetrahedra and LiO 3 triangular groups. The susceptibility measurements suggest a bidimensional antiferromagnetic behavior between 12 and 20 K, whereas a peak at 10 K is attributed to canting phenomena.

๐Ÿ“œ SIMILAR VOLUMES

A Sodium Molybdenyl Monophosphate with a
A Sodium Molybdenyl Monophosphate with an Intersecting Tunnel Structure: Na3(MoO)2(PO4)3
โœ S. Ledain; A. Leclaire; M.M. Borel; B. Raveau ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 776 KB

A new sodium molybdenyl monophosphate Na 3 (MoO) 2 (PO 4 ) 3 has been synthesized. It crystallizes in the space group C2/c with a โ€ซุโ€ฌ 15.211(2) A s s , b โ€ซุโ€ฌ 8.909(1) A s s , c โ€ซุโ€ฌ 9.362(1) A s s , and โ€ซุโ€ฌ 115ยฐยฐ99(1). The [Mo 2 P 3 O 14 ] three-dimensional framework can be described from isolated Mo

Mixed Valent Molybdenum Monophosphates w
Mixed Valent Molybdenum Monophosphates with an Intersecting Tunnel Structure: A3O2(MoO)4(PO4)4 (A = Rb, Tl)
โœ M.M. Borel; A. Leclaire; A. Guesdon; A. Grandin; B. Raveau ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 307 KB

New mixed valent monophosphates \(A_{3} \mathrm{O}_{2}\left(\mathrm{MoO}_{4}\right)_{4}\left(\mathrm{PO}_{4}\right)_{4}\) with an intersecting tunnel structure have been isolated for \(A=\mathrm{Rb}, \mathrm{Tl}\). The structure of the \(\mathrm{Rb}-\) phase has been solved from a single crystal X-r

Mo(V) Phosphates with an Opened Framewor
Mo(V) Phosphates with an Opened Framework: Li4โˆ’xA+x(MoO)3(PO4)3P2O7(A=Na, Ag, Cs, K), Li4โˆ’xBa2+x/2(MoO)3(PO4)3P2O7
โœ S. Ledain; A. Leclaire; M.M. Borel; M. Hervieu; J. Provost; B. Raveau ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 514 KB

The exploration of Li+A+Mo+P+O systems has allowed several Mo(V) phosphates, Li 4ุŠx A x (MoO) 3 (PO 4 ) 3 P 2 O 7 (A โ€ซุโ€ฌ Na, Ag, Cs, K) and Li 3 Ba 0.5 (MoO) 3 (PO 4 ) 3 P 2 O 7 , to be synthesized. Two types of closely related structures are evidenced depending on the nature and content of the A ca