A new molybdenum monophosphate \(\mathrm{Na}_{3}\left(\mathrm{MoO}_{4}\right)_{4}\left(\mathrm{PO}_{4}\right)_{5}\) has been synthesized. It crystallizes in the space group \(\mathrm{C} 2 / \mathrm{c}\) with \(a=16.789(1), b=8.500(1), c=16.361(1) \AA, \beta=126.34(1)^{\circ}\). Its tridimensional fr
A Mo(V) Monophosphate with an Original Tridimensional Framework: Li2Na(MoO)2(PO4)3
β Scribed by S. Ledain; A. Leclaire; M.M. Borel; B. Raveau
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 367 KB
- Volume
- 129
- Category
- Article
- ISSN
- 0022-4596
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π SIMILAR VOLUMES
New mixed valent monophosphates \(A_{3} \mathrm{O}_{2}\left(\mathrm{MoO}_{4}\right)_{4}\left(\mathrm{PO}_{4}\right)_{4}\) with an intersecting tunnel structure have been isolated for \(A=\mathrm{Rb}, \mathrm{Tl}\). The structure of the \(\mathrm{Rb}-\) phase has been solved from a single crystal X-r
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