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A Modified Method for the Meerwein-Ponndorf-Verley Reduction

✍ Scribed by Truett, W. L.; Moulton, W. N.

Book ID
126922067
Publisher
American Chemical Society
Year
1951
Tongue
English
Weight
297 KB
Volume
73
Category
Article
ISSN
0002-7863

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## Abstract The new variation of the Meerwein‐Ponndorf‐Verley reduction using 1‐[4‐(dimethylamino)phenyl]ethanol (DMAPE) (6) or 1‐tetralol (12) (3 equiv.) as the reducing alcohols and Zr(O‐__t__Bu)~4~ as the catalyst (0.2 equiv.) is kinetically controlled and highly stereoselective. Preferential ax