A modified arrhenius equation
โ Scribed by Kazutaka Nakamura; Toshiyuki Takayanagi; Shin Sato
- Book ID
- 103029769
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 224 KB
- Volume
- 160
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
The Arrhenius equation has been modified so as to express rate constants obtained at low temperatures: k=A exp [ --ED/
R( Tz +T')"*].
k is the rate constant, R the gas constant, T the absolute temperature, and A, E0 and T, are parameters. The applicability and implication of this modified equation are discussed.
๐ SIMILAR VOLUMES
Motivated by a recent mathematical paper, we discuss statistical parameter estimation in the Arrhenius equation, that relates kinetic reaction rates to temperature. In opposition to the paper in question, we argue theoretically for the appropriateness of using ordinary least squares on log-transform