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A MODIFICATION OF THE CURTIUS SYNTHESIS OF PRIMARY AMINES

โœ Scribed by Manske, Richard H. F.

Book ID
127174061
Publisher
American Chemical Society
Year
1929
Tongue
English
Weight
201 KB
Volume
51
Category
Article
ISSN
0002-7863

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๐Ÿ“œ SIMILAR VOLUMES

A facile synthesis of primary amines fro
A facile synthesis of primary amines from carboxylic acids by the curtius rearrangement
โœ Todd L. Capson; C.Dale Poulter ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 197 KB

Ab4tic.Z . 2-Trimethylsilylethanol was used to trap isocyanates produced by the Curtius rearrangement of acyl azides and the resulting trimethylsilylethyl carbamates were readily cleaved with tetra-n-butylammonium fluoride to liberate the primary amines.

Solid phase synthesis of aryl and hetero
Solid phase synthesis of aryl and heteroaryl amines using the Curtius rearrangement
โœ Satoshi Sunami; Takeshi Sagara; Mitsuru Ohkubo; Hajime Morishima ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

An efficient method for the solid phase synthesis of secondary ary| amines and heteroaryl amines was developed. The key step was the formation of aryl or heteroaryl carbamates using the Curtius rearrangement of aryl carboxylic acids with Wang resin as a trapping hydroxyl group. N-alkylation reaction