A study toward a total synthesis of fost
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Yohei Kiyotsuka; Junji Igarashi; Yuichi Kobayashi
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Article
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2002
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Elsevier Science
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French
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In order to synthesize the major C(3) C( ) part of fostriecin, asymmetric dihydroxylation of several dienes 5a-f, prepared by cross-coupling reactions of several types, was studied, thus providing high dependency on the hydroxyl groups at C(5) and C(11). The best regioselectivity was obtained with 5