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A Model of the Transition State in the Alkaline Phosphatase Reaction

✍ Scribed by Holtz, K. M.; Stec, B.; Kantrowitz, E. R.


Book ID
126899236
Publisher
The American Society for Biochemistry and Molecular Biology
Year
1999
Tongue
English
Weight
836 KB
Volume
274
Category
Article
ISSN
0021-9258

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A logically derived mechani.~tic model is presented for the Mikami enantioselective ene reaction which correedy describes the absolute and relative stereochemistry resulting from transition-state slnlctur~ sltlch as 3 and 5.