## Abstract Evidence is presented for the involvement of pentaco‐ordinated phosphorus intermediates in the rate‐determining step of the de‐alkylation reactions of some phosphates and phosphonates with LiCl and LiBr. Such involvement is suggested to lead to the zwitterionic pentaco‐ordinated phospho
✦ LIBER ✦
A model description for the initiation of conformational changes in DNA via the P(IV) residues. Part I
✍ Scribed by Henk Buck
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 124 KB
- Volume
- 99
- Category
- Article
- ISSN
- 0165-0513
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✦ Synopsis
Abstract
A mechanistic model is presented for the conversion of right‐handed DNA into left‐handed DNA. In this model the co‐ordination of phosphorus plays a key role.
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