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A mild palladium(II) catalyzed desilylation of phenolic t-butyldimethylsilyl ethers

✍ Scribed by Noel S Wilson; Brian A Keay


Book ID
103401999
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
189 KB
Volume
37
Category
Article
ISSN
0040-4039

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Mild base mediated desilylation of vario
✍ Noel S. Wilson; Brian A. Keay πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 186 KB

A variety of phenolic silyl ethers are easily desilylated in good to excellent yields by treatment with 1.1 equivalents of K2CO3, and ethanol containing 5 equivalents of water.

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A mild, efficient and selective deprotec
✍ Zhi-Yong Jiang; Yan-Guang Wang πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 143 KB

A mild and efficient method for the deprotection of aryl t-butyldimethysilyl (TBS) ethers is described. The protecting group TBS could be cleaved from aryl silyl ethers using cesium carbonate in DMF-H 2 O at room temperature to give the corresponding phenols in excellent yields. The reaction conditi