𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A mild and efficient method for esterification and transesterification catalyzed by iodine

✍ Scribed by K Ramalinga; P Vijayalakshmi; T.N.B Kaimal


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
514 KB
Volume
43
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis


Iodine, was found to be a practical and useful Lewis acid catalyst for the esterification of carboxylic acids with alcohols. The high catalytic activity of iodine can be used for the transesterification of esters by different alcohols including tertiary alcohols and sterically hindered primary and secondary alcohols. The method presented is especially effective for simultaneous esterification and transesterification reactions.


πŸ“œ SIMILAR VOLUMES


A mild and efficient method for the regi
✍ Marı́a Isabel Rodrı́guez-Franco; Isabel Dorronsoro; Ana I HernΓ‘ndez-Higueras; Ge πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 54 KB

The iodination of N-H or N-benzylpyrazoles using elemental iodine in the presence of CAN as the in situ oxidant is a mild and efficient method to prepare 4-iodopyrazoles containing even electron-withdrawing substituents. The reaction is regioselective since the iodine atom preferred pyrazole instead