A Methylene-di-λ5-phosphazene by Amide Cleavage of Tetramethylphosphonium Salts

Supramolecular Catalysis of Ester and Am

Supramolecular Catalysis of Ester and Amide Cleavage by a Dinuclear Barium(II) Complex

✍ Roberta Cacciapaglia; Stefano Di Stefano; Erik Kelderman; Luigi Mandolini 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 134 KB

Five components spontaneously self-assemble to yield the productive complex 1, where one barium ion delivers an ethoxide to the carbonyl group of an amide substrate anchored by means of a distal carboxylate moiety to the other barium ion. High substrate specificity, fairly high reaction rates with c