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A method for the selective reduction of carbohydrate 4,6-O-benzylidene acetals

✍ Scribed by Michael P. DeNinno; John B. Etienne; Kimberly C. Duplantier


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
168 KB
Volume
36
Category
Article
ISSN
0040-4039

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BH./Bu20T f is an effective reagent to reductively cleave 4,6-O-benzylidene acetals of various hexopyranosides to the corresponding 4-O-benzyl ethers. 4,6-O-Isopropylidene acetals can be similarly cleaved. Common protecting groups are stable to the reaction conditions.