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BoraneBu2BOTf: A mild reagent for the regioselective reductive ring opening of benzylidene acetals in carbohydrates

✍ Scribed by Lu Jiang; Tak-Hang Chan

Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 216 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)10599-8

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✦ Synopsis

BH./Bu20T f is an effective reagent to reductively cleave 4,6-O-benzylidene acetals of various hexopyranosides to the corresponding 4-O-benzyl ethers. 4,6-O-Isopropylidene acetals can be similarly cleaved. Common protecting groups are stable to the reaction conditions.

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