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A method for the regiospecific synthesis of enol triflates by enolate trapping

✍ Scribed by John E. Mc Murry; William J. Scott


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
158 KB
Volume
24
Category
Article
ISSN
0040-4039

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A new method for enol lactone synthesis
✍ Kennosuke Itoh; Shuji Kanemasa πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 120 KB

Reactions of cyclic 1,3-dicarbonyl compounds with 1-(2-alkenoyl)-4-bromo-3,5-dimethylpyrazoles under the double catalytic activation conditions using both catalytic amounts of Lewis acid and amine catalysts provide a new direct synthetic route to enol lactones. Thus, 1,3-cyclohexanedione is allowed