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A method for determining reactivity ratios whenn copolymerizations are influenced by penultimate group effects

โœ Scribed by C.A. Barson; D.R. Fenn


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
142 KB
Volume
23
Category
Article
ISSN
0014-3057

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A method for determining reactivity rati
โœ C.A. Barson; D.R. Fenn ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 143 KB

A novel kinetic treatment is proposed for the copolymerization of two monomers M~ and M 2 where the reactivities of all terminal groups are susceptible to penultimate group effects. By applying the conditions [Mt]>>[M2] and [MI]<<[M2], as is possible using radiolabelled monomers, values of r I and r