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A method for determining reactivity ratios in copolymerizations in the presence of a ceiling temperature effect

✍ Scribed by C.A. Barson; D.R. Fenn

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
194 KB
Volume
23
Category
Article
ISSN
0014-3057

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πŸ“œ SIMILAR VOLUMES

A method for determining reactivity rati
A method for determining reactivity ratios when copolymerizations are influenced by the penultimate group effects of both monomers
✍ C.A. Barson; D.R. Fenn πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 143 KB

A novel kinetic treatment is proposed for the copolymerization of two monomers M~ and M 2 where the reactivities of all terminal groups are susceptible to penultimate group effects. By applying the conditions [Mt]>>[M2] and [MI]<<[M2], as is possible using radiolabelled monomers, values of r I and r

A Linearization Procedure for the Determ
A Linearization Procedure for the Determination of the Radical Reactivity Ratios in Restricted Penultimate Copolymerization Systems
✍ Franz Hinkelmann; Oskar Friedrich Olaj; Irene SchnΓΆll-Bitai πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 273 KB

## Abstract A newly developed method for the determination of the radical reactivity ratios is presented. Two main equations are used and the parameters can be calculated from the ordinate and the slope of the linearization plots. Both equations yield identical values when applied to synthetic data

A Linearization Procedure for Determinin
A Linearization Procedure for Determining Radical Reactivity Ratios in Restricted Penultimate Copolymerization Systems, 2
✍ Franz Hinkelmann; Oskar Friedrich Olaj; Irene SchnΓΆll-Bitai; Gerhard Zifferer πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 365 KB

## Abstract A large number of the already published data of the experimental rate constants of propagation as a function of the monomer composition for copolymerization systems has been analyzed by applying a linearization procedure (introduced in the preceding publication) and new linear least squ