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A Metal-Templated 4 + 2 Cycloaddition Reaction of an Alkyne and a Diyne To Form a 1,2-Aryne

โœ Scribed by Tsui, Jordan A.; Sterenberg, Brian T.


Book ID
118052316
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
801 KB
Volume
28
Category
Article
ISSN
0276-7333

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[4 + 2] Cycloaddition Reactions of a 4a,
โœ Laue, Jรถrg ;Seitz, Gunther ๐Ÿ“‚ Article ๐Ÿ“… 2006 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 306 KB ๐Ÿ‘ 1 views

## Abstract The novel propellane 3 containing an electronโ€rich cyclohexadiene and an electronโ€deficient diazadiene system in one and the same molecule reacts site selectively with the electronโ€rich alkynes 4 and 8 as well as with cyclooctyne (10) to yield the interestingly substituted novel 1,6โ€met