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A Metal-Free General Procedure for Oxidation of Secondary Amines to Nitrones

✍ Scribed by Gella, Carolina; Ferrer, Èric; Alibés, Ramon; Busqué, Félíx; de March, Pedro; Figueredo, Marta; Font, Josep


Book ID
115444133
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
744 KB
Volume
74
Category
Article
ISSN
0022-3263

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Catalytic oxidation of secondary amines to nitrones using alkyl hydroperoxides as primary oxidant has been demonstrated for the first time. The titanium alkoxide catalyst is protected from co-product water by the combined use of a tightly binding trialkanolamine ligand and molecular sieves. Nitrones