The flash vacuum pyrolysis of 3,3,5,5-tetramethylpyrazolin-oxide 9 as the major products. The reaction of tetramethylallene 13 with oxygen atoms yields the same 4-one (4) with subsequent trapping of the products in argon at 10 K results in the formation of a complex product mixture product mixture o
A matrix isolation and flash photolysis study of the cyclization reactions of chromium amino carbenes
β Scribed by K.O Doyle; M.L Gallagher; M.T Pryce; A.D Rooney
- Book ID
- 108346762
- Publisher
- Elsevier Science
- Year
- 2001
- Tongue
- English
- Weight
- 199 KB
- Volume
- 617-618
- Category
- Article
- ISSN
- 0022-328X
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π SIMILAR VOLUMES
Rate constants of reaction of cyclopentadienylidene, fluorenylidene and tetrachlorocyclopentadienylidene with alcohols and other quenchers were determined by laser flash photolysis methods. The rate constants of reaction of cyclopentadienylidene and fluorenylidene with various alcohols were determin
T h e flash photolysis of azo-n-propane and of azoisopropane has been studied by kinetic spectroscopy. Transient absorption spectra in the region of 220-260 nm have been assigned to the n-propyl and isopropyl radicals. For the n-propyl radical, cmax = 744 f 39 limo1 cm a t 245 nm and the rate consta