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The reaction of cyclopentadienylidine, fluorenylidene and tetrachlorocyclopentadienylidene with alcohols. A laser flash photolysis study

✍ Scribed by David R. Olson; Matthew S. Platz

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 763 KB
Volume: 9
Category: Article
ISSN: 0894-3230
DOI: 10.1002/(sici)1099-1395(199611)9:11<759::aid-poc834>3.0.co;2-o

No coin nor oath required. For personal study only.

✦ Synopsis

Rate constants of reaction of cyclopentadienylidene, fluorenylidene and tetrachlorocyclopentadienylidene with alcohols and other quenchers were determined by laser flash photolysis methods. The rate constants of reaction of cyclopentadienylidene and fluorenylidene with various alcohols were determined and found to increase with increasing alcohol acidity. Alcohols as a group reacted faster with cyclopentadienylidene and fluorenylidene than likely ylide formers such as pyridine, ethyl acetate and tetrahydrofuran. Br~nsted plots of the reaction of cyclopentadienylidene and fluorenylidene with alcohols are linear with slopes of 0.061 and 0.082, respectively. In the case of tetrachlorocyclopentadienylidene, an ylide type of reaction mechanism with alcohols is indicated. Tetrachlorocyclopentadienylidene reacts most rapidly with the least acidic alcohol studied and this carbene reacts more rapidly with tetramethylurea, pyridine and tetrahydrofuran than with methanol.

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