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A mass spectrometric study of the vaporization of boron phosphate (BPO4)

✍ Scribed by Dr. S. I. Lopatin; G. A. Semenov


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
37 KB
Volume
13
Category
Article
ISSN
0951-4198

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✦ Synopsis


The vaporization behavior of boron phosphate has been studied by using Knudsen effusion mass spectrometry. The vapor over BPO 4 consists of B 2 O 3 , P 4 O 10 , PO 2 , BPO 4 (platinum cell) and B 2 O 3 , PO, PO 2 , BPO 3 , BPO 4 (molybdenum cell). Standard enthalpies of formation and atomization (kJ/mol) were derived for BPO 4 (g) (Γ€1000 AE 15 and 2863 AE 16) and for BPO 3 (g) (Γ€731 AE 15 and 2347 AE 16), respectively.


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