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A Mass-Spectrometric Investigation of CxNO2 (x=1, 2) Ions and Neutrals

✍ Scribed by Sülzle, Detlev ;O'Bannon, P. E. ;Schwarz, Helmut


Publisher
Wiley (John Wiley & Sons)
Year
1992
Tongue
English
Weight
413 KB
Volume
125
Category
Article
ISSN
0009-2940

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✦ Synopsis


The isomeric [C2,N,02]+ ions OCNCO+, OCCNO+, and NCCO, have been generated and structurally characterized on the basis of their collisional activation, charge reversal, and neutralization-reionization mass spectra. The open-shell neu-trals formed in the neutralization step undergo facile unimolecular decomposition. A recovery signal is obtained only for OCCNO.


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The mass spectrometric characterization of a series of [ReOX(PY),] complexes containing bidentate phosphinoenolate and phosphinoamine ligands has been achieved by electron impact mass spectrometry and metastable ion studies. The data obtained showed a higher stability of the complexes bearing the ph