✦ LIBER ✦

A Mass Spectrometric Investigation of a Series of [ReOX(PY)2] Complexes Containing Bidentate Phosphinophenolate and Phosphinoamine Ligands

✍ Scribed by Silvia Catinella; Francesco Tisato; Fiorenzo Refosco; Cristina Bolzati; Pietro Traldi

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 375 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(19960731)10:10<1295::aid-rcm585>3.0.co;2-h

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✦ Synopsis

The mass spectrometric characterization of a series of [ReOX(PY),] complexes containing bidentate phosphinoenolate and phosphinoamine ligands has been achieved by electron impact mass spectrometry and metastable ion studies. The data obtained showed a higher stability of the complexes bearing the phosphinoenolate ligand with respect to the phosphinoamine ligand. An increase in the stability of the complexes by decreasing the atomic radius of the halogen was also observed.