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A manganese(V)-oxo complex

✍ Scribed by Collins, Terrence J.; Gordon-Wylie, Scott W.

Book ID
120444419
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
443 KB
Volume
111
Category
Article
ISSN
0002-7863

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## Abstract The intrinsic reactivity of a manganese(V)‐oxo porphyrin complex, a typically fleeting intermediate in catalytic oxidation reactions in solution, has been elucidated in a study focused on its gas‐phase ion‐chemistry. The naked high‐valent Mn^V^‐oxo porphyrin intermediate **1** ([(tpfpp)