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Synthesis, Characterization, and Reactivities of Manganese(V)−Oxo Porphyrin Complexes

✍ Scribed by Song, Woon Ju; Seo, Mi Sook; DeBeer George, Serena; Ohta, Takehiro; Song, Rita; Kang, Min-Jung; Tosha, Takehiko; Kitagawa, Teizo; Solomon, Edward I.; Nam, Wonwoo


Book ID
121872637
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
240 KB
Volume
129
Category
Article
ISSN
0002-7863

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## Abstract The intrinsic reactivity of a manganese(V)‐oxo porphyrin complex, a typically fleeting intermediate in catalytic oxidation reactions in solution, has been elucidated in a study focused on its gas‐phase ion‐chemistry. The naked high‐valent Mn^V^‐oxo porphyrin intermediate **1** ([(tpfpp)