The first total synthesis of haliclamine A (1), a macrocyclic marine alkaloid closely related to the key bisdihydropyridine intermediate 3 of the biogenetically unique manzamine family, has been efficiently achieved via stepwise inter-and intramolecular N-alkylations of 3-alkylpyridine derivatives 2
✦ LIBER ✦
A Macrocyclic β-Iodoallenolate Intermediate Is Key: Synthesis of the ABD Core of Phomactin A
✍ Scribed by Ciesielski, Jennifer; Cariou, Kevin; Frontier, Alison J.
- Book ID
- 118007219
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 448 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1523-7060
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