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A Li10 Cage Containing the [C6H11P⋅⋅⋅–C(Ph)⋅⋅⋅–N]2− Ion: Umpolung in the Oligomerization of a Nitrile

✍ Scribed by Neil Feeder; Yvonne G. Lawson; Paul R. Raithby; Jeremy M. Rawson; Alexander Steiner; Jody A. Wood; Anthony D. Woods; Dominic S. Wright


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
118 KB
Volume
39
Category
Article
ISSN
0044-8249

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The structure of 1 is built up from FeMo 12 (H 2 PO 4 ) 6 (PO 4 ) 2 (OH) 6 O 4؊ 24 cluster anions connected to each other via hydrogen bonds. The arrangement of clusters is such that each cluster is surrounded by six equivalent anions resulting in three-dimensional cavities. The charge balancing cat