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A kinetic study of the oxidation of Ti(III) to Ti(IV) in hydrofluoric acid solutions

✍ Scribed by J.W. Johnson; K.S. Shen; W.J. James

Book ID
116011298
Publisher
Elsevier Science
Year
1968
Weight
470 KB
Volume
15
Category
Article
ISSN
0022-5088

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## Abstract The oxidation of __trans__‐stilbene, phenylacetylene, and diphenylacetylene by Tl(OAc)~3~ in aqueous acetic acid medium in the presence of HClO~4~ follows the rate law in [H^+^] of 0.1–1.0__M__, the [H^+^] dependence below 0.1__M__ being marginal. The reactions are strongly dielectric